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十六烷基三甲基铵C60盐的合成和性质
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摘要:
采用钠萘作还原剂制备C60负一价离子,计量易控制,方法简便。利用复分解反应首次合成了十六烷基三甲基铵的C60盐,产物经UV-NIR、IR、ESI-MS表征,并研究了其ESR性质和被空气氧化的过程。
关键词:  C60负离子 十六烷基三甲基铵 合成 氧化 性质 结构表征 钠萘
DOI:
修订日期:2001-09-29
基金项目:安徽省自然科学基金;45122;
Synthesis and Properties of Hexadecyl Trimethyl Ammonium Buckminsterfulleride
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Abstract:
C - 60 anion was obtained by using potassium naphthalide as a reductant, which is a facile method and easy to control the stoichiometry of reductant. Hexadecyl trimetnyl ammonium buckminsterfulleride was first synthesized by metathetical reaction. The product was characterized by UV NIR, IR, ESI MS, its ESR and the oxidation reaction were also studied
Key words:  buckminsterfulleride,hexadecyl trimethyl ammonium,synthesis,oxidation

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